一、 个人简介
刘松,男,最高学历:博士研究生,副教授,重庆文理学院材料与化工硕士专业学位点首批导师,环境材料与修复技术重庆市重点实验室专职科研人员。
二、研究方向
1. 过渡金属催化碳-氢键、碳碳键活化反应机理
2. 过渡金属催化烯烃双官能化反应机制及反应模式
3. 自由基偶联反应相关机制及反应模式
三、 承担课程
《物理化学》《有机化学》
四、 科研项目与学术成果
1. 科研项目
(1)镍催化偶联反应中高自旋镍物种电子转移模式的理论研究,国家自然科学基金青年科学基金项目(22303010)
(2)活性开壳层过渡金属的结构、性质及催化偶联反应机制的理论研究,国家自然科学基金面上项目(22271034)
(3)镍催化烯烃1,n -双官能化成键新模式探究,重庆市科委面上项目(cstc2021jcyj-msxmX0593)
(4)铜催化烯烃不对称双官能化机理及反应模式的理论研究,重庆市教委青年项目(KJQN202101301)
(5)镍催化烯烃双官能化机理及反应模式探究,文理学院自然科学重大培育项目(P2021HH03)
(6)铑催化碳-硅键、碳-碳键活化新模式的理论研究,文理学院引进人才项目(R2020SHH01)
2. 学术成果
(1)发表论文
[1] Song Liu*; Dianmin Zhang; Xiaoqing Zhang; Yuyan Cheng; Hong Deng. Investigation of the activation mode of vinylarene in Giri’s Ni-catalyzed vinylarene intermolecular 1,2-alkylarylation cross-coupling: a theoretical study, Org. Chem. Front., 2023, 10, 4359–4367.
[2] Song Liu*; Dianmin Zhang; Min Xiao; Chengling Pu; Xiaoqing Zhang; Xiuwen Yang; Tao Zhang*; Ruopeng Bai. C–N bond metathesis: mechanistic insight into palladium-catalyzed ring-closing using aminal species. Org. Chem. Front., 2023, 10, 181–188.
[3] Song Liu*; Dianmin Zhang; Chuanjia Li; Dongli Li; Zhuanzhuan Zhou. Theoretical Study of Rhodium-Catalyzed Dual C?H Activation to Synthesize C?N Axially Chiral N?Aryloxindoles: Origin of Axial Chirality, Organometallics 2022, 41, 1275-1283.
[4] Dianmin Zhang; Xiaofang He; Tao Yang; Song Liu* Insights into the Activation Mode of α-Carbonyl Sulfoxonium Ylides in Rhodium-Catalyzed C-H Activation: A Theoretical Study, ChemistryOpen 2022, 11, e202100254.
[5] Yuan Huang#; Chao Ma#; Song Liu#; Li-Cheng Yang; Yu Lan*; Yu Zhao*. Ligand coordination- and dissociation induced divergent allylic alkylations using alkynes, Chem, 2021, 3, 812-826.(共同一作)
[6] Yong Chen, Hai-Lun Wan, Yuan Huang, Song Liu, Feiyi Wang, Cuifen Lu, Junqi Nie, Zuxing Chen, Guichun Yang,*; Chao Ma*. B(C6F5)3?Catalyzed β?Functionalization of Pyrrolidines Using Isatins via Borrowing Hydrogen: Divergent Access to Substituted Pyrrolidines and Pyrroles, Organic Letters, 2021, 22, 7797-7803.
[7] Dan Heng, Haohua Chen, Xiaoqian He, Song Liu, Lei Zhu, Kangbao Zhong, Tao Zhang, Ruopeng Bai,* and Yu Lan*; Synergistic Dinuclear Rhodium Induced Rhodium-Walking Enabling Alkene Terminal Arylation: A Theoretical Study, ACS Catalysis, 2021, 11, 3975-3987.
[8] Haohua Chen, Yuanyuan Li*, Song Liu, Qin Xiong, Ruopeng Bai, Donghui Wei*, Yu Lan* On the mechanism of homogeneous Pt-catalysis: A theoretical view, Coordination Chemistry Reviews, 2021, 437, 21863.
[9] Itsuki Nohira; Song Liu; Ruopeng Bai; Yu Lan*; Naoto Chatani*; Nickel-Catalyzed C?F/N?H Annulation of Aromatic Amides with Alkynes: Activation of C?F Bonds under Mild Reaction Conditions, Journal of the American Chemical Society, 2020, 142, 17306-17311.
[10] Song Liu; Xiaotian Qi*; Ruopeng Bai; Yu Lan*; Theoretical Study of Ni-Catalyzed C?N Radical?Radical Cross-Coupling, The Journal of Organic Chemistry, 2019, 84, 3321-3327.
[11] Yidong Liu#; Song Liu#; Dongmei Li; Nan Zhang; Lei Peng; Jun Ao; Choong Eui Song; Yu Lan*; Hailong Yan*; Kinetic Resolution of Allylic Alcohol with Chiral BINOL-Based Alkoxides: A Combination of Experimental and Theoretical Studies, Journal of the American Chemical Society, 2018, 141, 1150-1159. (共同一作)
[12] Song Liu; Tao Zhang; Lei Zhu; Kangbao Zhong; Jianxian Gong; Zhen Yang*; Ruopeng Bai*; Yu Lan*; Retro-metal-ene versus retro-Aldol: mechanistic insight into Rh-catalysed formal [3+2] cycloaddition, Chemical Communications, 2018, 54, 13551-13554.
(2)获取专利
(3)专著/教材
《Computational Advances of Rh-Catalyzed C–H Functionalization From Elementary Reaction to Mechanism》、出版社:Springer、作者: Yu Lan · Cheng-Xing Cui · Song Liu ·Chun-Xiang Li · Ruopeng Bai、ISBN:978-981-16-0431-7。
(4)获奖情况
2018年重庆市自然科学一等奖(第二完成人),题为:四取代碳手性中心的构建。
五、、 联系方式
邮 箱:sliu@cqwu.edu.cn
邮 编:402160
通讯地址:重庆市永川区重庆文理学院红河校区B区